Search results for " PHOTOCATALYTIC REACTION"
showing 2 items of 2 documents
Comparison between catalytic and catalytic photo-assisted propene hydration by using supported heteropolyacid
2012
Abstract Hybrid materials have been prepared by impregnation of the heteropolyacid H 3 PW 12 O 40 on commercial TiO 2 . The polyoxometalates (POM) amount deposited was 15, 30, 50 and 70% with respect to the weight of the TiO 2 support. Moreover two samples containing a POM amount of 15, and 50% with respect to the weight of SiO 2 were also prepared for the sake of comparison. All prepared samples were efficient catalysts for the hydration of propene to 2-propanol in gas–solid regime at atmospheric pressure and at temperatures ranging between 50 and 85 °C. The study carried out on the hybrid TiO 2 based materials evidenced that, as far as the catalytic activity is concerned, exists an optimu…
Photocatalytic and Catalytic Reactions in Gas–Solid and in Liquid–Solid Systems
2019
Abstract Heterogeneous photocatalytic and thermal-catalytic reactions are here presented focusing the differences and similarities between the two processes. When possible, the comparison was made for the same chemical reaction in the presence of an inorganic material playing the role of both catalyst or/and photocatalyst. Several examples are presented where a catalytic reaction can occur at milder experimental conditions and, particularly, at lower temperature when the system is also irradiated by UV and/or visible light. The differences in mechanistic aspects, conversions, and selectivities between catalytic and photocatalytic reactions will be also considered because these occurrences a…